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Bromine production in the United States
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Bromine production in the United States : ウィキペディア英語版
Bromine production in the United States
__NOTOC__
Bromine production in the United States of 225,000 tonnes in 2013 made that country the second-largest producer of bromine, after Jordan. The US supplied 29 percent of world production. Since 2007, all US bromine has been produced by two companies in southern Arkansas, which extract bromine from brine pumped from the Smackover Formation. At an advertised price of US$3.50 to US$3.90 per kg, the US 2013 US production would have a value of roughly US$800 million.
The two active bromine producers are Albemarle Corporation and Chemtura, whose bromine operations together employ 950 people. Albemarle Corporation, whose corporate headquarters is in Baton Rouge, Louisiana, operates two main plants at Magnolia, in Columbia County, Arkansas, and some satellite plants in Union County. In 2007, Albemarle had capacity to produce 148,000 tons of bromine per year.
Chemtura, a Philadelphia-based corporation, operates four plants through its subsidiary, Great Lakes Solutions. Three plants are in the vicinity of El Dorado, and all in Union County, Arkansas. In 2007, Chemtura had the capacity to produce 130,000 tonnes of bromine per year.
Since 1969, all US bromine has been produced from subsurface brine. Previously, bromine was also recovered from sea water, either directly or from the bittern produced during solar salt operations.
==Geology==
Bromine-bearing brines are associated with saline deposits. The bromine content of sea water is 60 to 70 parts per million (ppm). As sea water evaporates, a succession of minerals precipitate, concentrating the bromine. Bromide is so soluble that it does not form saline minerals. After halite (rock salt) precipitates, the remaining brine, called bittern, contains about 2,700 ppm bromine. Bromine continues to concentrate as magnesium and potassium minerals precipitate. The brine remaining after potassium mineral precipitation may contain 6,000 ppm bromine.〔P. Evan Dresel and Arthur W Rose, ''Chemistry and Origin of Oil and Gas Well Brines in Western Pennsylvania'', Pennsylvania Dept. of Conservation, Open-File Report OFOG 10-01.0, 2010.〕
Underground sources of bromine-rich brines are associated with halite deposits. The process of concentrating bromine by evaporation artificially to produce sea salt replicates the natural process, and produces bromine-rich brine.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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